Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media.
نویسندگان
چکیده
Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.
منابع مشابه
Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic mediaw
O2 reduction by ferrocene and its derivatives in organic media in the presence of an acid, such as trichloroacetic and trifluoroacetic acids and perchloric acid, has been known for many years. Recently, O2 reduction has also been studied in biphasic systems composed of an organic solvent containing a ferrocene derivative in contact with an aqueous inorganic acid solution containing a very lipop...
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1572-6657/$ see front matter 2009 Elsevier B.V. A doi:10.1016/j.jelechem.2009.11.029 * Corresponding author. Fax: +41 21 6933667. E-mail address: [email protected] (H.H. Girau 1 Present address: Institute of Microanalytical Syste Zhejiang University, 310058 Hangzhou, China. Molecular oxygen (O2) reduction by decamethylferrocene (DMFc) was investigated at a polarized water/ 1,2-dichloroetha...
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 17 شماره
صفحات -
تاریخ انتشار 2010